ẢNH HƯỞNG CỦA THỜI GIAN KHUẤY Ủ NHIỆT ĐẾN QUÁ TRÌNH TỔNG HỢP XÚC TÁC NANO TỪ TÍNH CUFE2O4 BẰNG PHƯƠNG PHÁP ĐỒNG KẾT TỦA VÀ ỨNG DỤNG TRONG PHẢN ỨNG KHỬ NHANH p-NITROANILINE
Nội dung chính của bài viết
Tóm tắt
Trong nghiên cứu này, các hạt nano từ tính CuFe2O4 đã được tổng hợp bằng kỹ thuật đồng kết tủa - khuấy ủ nhiệt trong các khoảng thời gian khác nhau nhằm ứng dụng làm xúc tác cho phản ứng khử p-nitroaniline ở nhiệt độ phòng. Kết quả cho thấy các mẫu xúc tác khi được tổng hợp bằng phương pháp này đều thể hiện cấu trúc pha spinel ổn định, cùng hàm lượng ion kim loại trên bề mặt tăng dần theo thời gian khuấy ủ nhiệt, từ đó cho phép chuyển hóa hoàn toàn p-nitroaniline thành p-phenylenediamine chỉ trong khoảng 1,25 phút. Ngoài ra, những vật liệu CuFe2O4 này còn có thể dễ dàng được thu hồi bằng nam châm và có thể tái sử dụng trong nhiều chu kỳ liên tiếp.
Từ khóa
CuFe2O4, phương pháp đồng kết tủa – khuấy ủ nhiệt, xúc tác từ tính, khử p-nitroaniline, p-phenylenediamine.
Chi tiết bài viết
Tài liệu tham khảo
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[3] Ma, H., Yao, S., Zhang, J., Pu, C., Zhao, S., Wang, M., and Xiong, J. Steady-state and transient photolysis of p-nitroaniline in acetonitrile. Journal of Photochemistry and Photobiology A: Chemistry, vol. 202, n.1, p. 67-73, 2009.
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[6] Gharaghani, M. A., Samaei, M., Mahdizadeh, H., Nasiri, A., Keshtkar, M., Mohammadpour, A., and Khaneghah, A. M. An effective magnetic nanobiocomposite: Preparation, characterization and its application for adsorption removal of P-nitroaniline from aquatic environments. Environmental Research, vol. 246, p. 118128, 2024.
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[15] Sharj-Sharifi, M., Taghvaei-Ganjali, S., and Motiee, F. The effect of protecting waxes on staining antidegradant performance in tyre sidewall formulation. Journal of Rubber Research, vol. 23, n. 2, p. 111-124, 2020.
[16] Al-Enezi, M. H., and Aldawsari, F. S. Study of P-phenylenediamine (PPD) concentrations after hair dye mixing: a call for safety reassessment. Cosmetics, vol. 9, n.2, p. 41, 2022. [17] Ahmed, M. A., Ahmed, M. A., and Mohamed, A. A. Removal of 4-nitrophenol and indigo carmine dye from wastewaters by magnetic copper ferrite nanoparticles: Kinetic, thermodynamic and mechanistic insights. Journal of Saudi Chemical Society, vol. 27, n. 6, p. 101748, 2023.
[18] Naghash-Hamed, S., Arsalani, N., and Mousavi, S. B. Facile fabrication of CuFe2O4 coated with carbon quantum dots nanocomposite as an efficient heterogeneous catalyst toward the reduction of nitroaniline compounds for management of aquatic resources. Journal of Photochemistry and Photobiology A: Chemistry, vol. 443, p. 114822, 2023.
[19] Amani, A., Derikvand, Z., and Ghadermazi, M. Modification of new magnetic nanocomposites Bi2WO6/CuFe2O4 and its excellent catalytic reduction for toxic nitroaromatic compounds and chromium (VI). Inorganic and Nano-Metal Chemistry, vol. 55, n. 7, p. 864-879, 2025.
[20] Sahoo, A., Acharya, A. N., Jena, P., Moonis, M., Biswal, J. P., Swain, S., and Tripathy, M. C. Zirconium ferrite nanoparticles as smart materials for energy and environmental applications: fractional-order supercapacitors, reservoirs of F− ions, and efficient electrocatalysts for water splitting. Nanoscale Advances, vol. 7, p. 6575-6595, 2025.
[21] Sebah, I., and Belmouden, M. Copper ferrite–graphene oxide catalyst for enhanced peroxymonosulfate activation and pollutant degradation. Nanoscale Advances, vol. 7, p. 5646, 2025.
[22] Akbar, A., Howlader, A., Islam, Q. A., Chatterjee, T., and Ghosh, M. Magnetically recoverable biogenic CuFe2O4 nanoparticles for sustainable catalytic degradation of organic dyes. Journal of Water Process Engineering, vol. 79, p. 108871, 2025.
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[24] Suzuki, S., Takeoka, Y., Rikukawa, M., and Yoshizawa-Fujita, M. Brønsted acidic ionic liquids for cellulose hydrolysis in an aqueous medium: structural effects on acidity and glucose yield. RSC advances, vol. 8, n. 26, p. 14623-14632, 2018.
[25] Maiti, S., Sinha, S. S., Suchowski, H., and Singh, M. Process parameter optimization for the detoxification of emerging environmental pollutant, PPD. Journal of Hazardous Materials Advances, vol. 10, p. 100290, 2023.
[26] Du, M., Liu, Q., Huang, C., and Qiu, X. One-step synthesis of magnetically recyclable Co@ BN core–shell nanocatalysts for catalytic reduction of nitroarenes. RSC advances, vol. 7, n.56, p. 35451-35459, 2017.
[27] Ngo, D. T., Tran, T. T. T., Nguyen, T. L., Hoang, C. N., Tran‐Thuy, T. M., Luu, T. X.T., and Le, T. K. Microwave-assisted synthesis of magnetic CuFe2O4 nanocatalysts for rapid room-temperature reduction of 4-nitroaniline. Journal of Chemical Technology and Biotechnology, vol. 100, n. 10, p. 2163-2175, 2025.
[28] Jayachandrabal, B., Tikker, P., and Preis, S. Oxidation of aqueous p-Nitroaniline by pulsed corona discharge. Separation and Purification Technology, vol. 297,p. 121473, 2022.
[29] Jeon, K. W., Park, J. W., Lee, R. R., Gong, J. H., Jang, W. J., Shim, J. O. and Ju, Y.
W. Facile synthesis of CuFe2O4 catalyst by the electrospinning method to produce hydrogen via the water gas shift of waste-derived syngas. Journal of Environmental Chemical Engineering, vol. 11, n. 3, p. 110105, 2023.
[30] Zarei, M., Mohammadzadeh, I., Saidi, K. and Sheibani, H. Fabrication of biochar@ Cu-Ni nanocatalyst for reduction of aryl aldehyde and nitroarene compounds. Biomass Conversion and Biorefinery, vol. 14, n. 2, p. 2761-2776, 2024.
[31] Ansari, A., Badhe, R. A. and Garje, S. S. Preparation of CdS–TiO2-based palladium heterogeneous nanocatalyst by solvothermal route and its catalytic activity for reduction of nitroaromatic compounds. ACS omega, vol. 4, n. 12, p. 14937-14946, 2019.
[32] Maleki, M. H., Shirani, M. A. and Dinari, M. Facile synthesis of green and efficient copper-based magnetically recoverable nanocatalyst for the reduction of nitrophenol derivatives. Journal of Molecular Liquids, vol. 365, p. 120189, 2022. [33] Kumbhar, G. S., Patil, S. V., Sarvalkar, P. D., Vadanagekar, A. S., Karvekar, O. S., Patil, S. S., Rane, M. R., Kurhe, D. N. and Prasad, N. R. Synthesis of a Ag/rGO nanocomposite using Bos taurus indicus urine for nitroarene reduction and biological activity. RSC advances, vol. 12, n. 55, p. 35598-35612, 2022.
[34] Yulizar, Y., Apriandanu, D. O. B. and Zahra, Z. A. SiO2/NiFe2O4 nanocomposites: Synthesis, characterization and their catalytic activity for 4-nitroaniline reduction. Materials Chemistry and Physics, vol. 261, p. 124243, 2021.
[35] Naghash‐Hamed, S., Arsalani, N. and Mousavi, S. B. The catalytic reduction of nitroanilines using synthesized CuFe2O4 nanoparticles in an aqueous medium. ChemistryOpen, vol. 11, n. 11, p. e202200156, 2022.
[2] Li, M., Cao, H., Han, D., Li, X., and He, M. Kinetics and mechanism of the reactions of OH radicals with p-nitroaniline in gas-phase and aqueous solution. Computational and Theoretical Chemistry, vol. 1055, p. 68-77, 2015.
[3] Ma, H., Yao, S., Zhang, J., Pu, C., Zhao, S., Wang, M., and Xiong, J. Steady-state and transient photolysis of p-nitroaniline in acetonitrile. Journal of Photochemistry and Photobiology A: Chemistry, vol. 202, n.1, p. 67-73, 2009.
[4] Nair, R. S., Auletta, C. S., Schroeder, R. E., and Johannsen, F. R. Chronic toxicity, oncogenic potential, and reproductive toxicity of p-nitroaniline in rats. Toxicological Sciences, vol. 15, n.3, p. 607-621, 1990.
[5] Rahmati, N., Hashemi, M., and Nasiri, A. Persulfate-enhanced photodegradation of para-nitroaniline in wastewater using AgCuFe2O4@ MC/AC as a newly synthesized heterogeneous magnetic nanophotocatalyst: Mechanism study and bioassay of effluent. Environmental Technology and Innovation, vol. 38, p. 104181, 2025.
[6] Gharaghani, M. A., Samaei, M., Mahdizadeh, H., Nasiri, A., Keshtkar, M., Mohammadpour, A., and Khaneghah, A. M. An effective magnetic nanobiocomposite: Preparation, characterization and its application for adsorption removal of P-nitroaniline from aquatic environments. Environmental Research, vol. 246, p. 118128, 2024.
[7] León, G., Hidalgo, A. M., Gómez, M., Gómez, E., and Miguel, B. Efficiency, Kinetics and Mechanism of 4-Nitroaniline Removal from Aqueous Solutions by Emulsion Liquid Membranes Using Type 1 Facilitated Transport. Membranes, vol. 14, n. 1, p.13, 2024.
[8] Jayachandrabal, B., Tikker, P., and Preis, S. Oxidation of aqueous p-Nitroaniline by pulsed corona discharge. Separation and Purification Technology, vol. 297,
p. 121473, 2022.
[9] Dapaah, M. F., Niu, Q., Yu, Y. Y., Jia, H., and Cheng, L. Tunning MIL-101 (Cr) MOF polymorphism towards efficient adsorption and localized Fenton-like degradation of para-nitroaniline by Fe incorporation. Chemical Engineering Journal, vol. 486, p. 150162, 2024.
[10] Malakootian, M., Khatami, M., Mahdizadeh, H., Nasiri, A., and Amiri Gharaghani, M.
A study on the photocatalytic degradation of p-Nitroaniline on glass plates by Thermo- Immobilized ZnO nanoparticle. Inorganic and Nano-Metal Chemistry, vol. 50, n. 3, p. 124-135, 2020.
[11] Das, P., Ghosh, S., and Baskey, M. Heterogeneous catalytic reduction of 4-nitroaniline by RGO-Ni nanocomposite for water resource management. Journal of Materials Science: Materials in Electronics, vol. 30, n. 22, p. 19731-19737, 2019.
[12] Din, M. I., Khalid, R., Hussain, Z., Najeeb, J., Sahrif, A., Intisar, A., and Ahmed, E. Critical review on the chemical reduction of nitroaniline. RSC advances, vol. 10, n. 32, p. 19041-19058, 2020.
[13] Abedinpour, S., Mahkam, M., and Zonouz, A. M. Graphenic molybdenum disulfide nanocomposites as heterogeneous nano-catalyst for reduction of nitroanilines. Journal of Photochemistry and Photobiology A: Chemistry, vol. 448, p. 115281, 2024.
[14] Selvarani, J. F. L., Pushpavalli, K. S., Kala, S. M. J., and Prakash, K. S. Eco-friendly synthesis of gold nanoparticles using Ruta graveolens Leaf extract and their efficient catalytic reduction of 4-Nitroaniline, Methylene Blue and Antibiotic Nitrofurantoin. Journal of Organometallic Chemistry, vol. 1036, p. 123706, 2025.
[15] Sharj-Sharifi, M., Taghvaei-Ganjali, S., and Motiee, F. The effect of protecting waxes on staining antidegradant performance in tyre sidewall formulation. Journal of Rubber Research, vol. 23, n. 2, p. 111-124, 2020.
[16] Al-Enezi, M. H., and Aldawsari, F. S. Study of P-phenylenediamine (PPD) concentrations after hair dye mixing: a call for safety reassessment. Cosmetics, vol. 9, n.2, p. 41, 2022. [17] Ahmed, M. A., Ahmed, M. A., and Mohamed, A. A. Removal of 4-nitrophenol and indigo carmine dye from wastewaters by magnetic copper ferrite nanoparticles: Kinetic, thermodynamic and mechanistic insights. Journal of Saudi Chemical Society, vol. 27, n. 6, p. 101748, 2023.
[18] Naghash-Hamed, S., Arsalani, N., and Mousavi, S. B. Facile fabrication of CuFe2O4 coated with carbon quantum dots nanocomposite as an efficient heterogeneous catalyst toward the reduction of nitroaniline compounds for management of aquatic resources. Journal of Photochemistry and Photobiology A: Chemistry, vol. 443, p. 114822, 2023.
[19] Amani, A., Derikvand, Z., and Ghadermazi, M. Modification of new magnetic nanocomposites Bi2WO6/CuFe2O4 and its excellent catalytic reduction for toxic nitroaromatic compounds and chromium (VI). Inorganic and Nano-Metal Chemistry, vol. 55, n. 7, p. 864-879, 2025.
[20] Sahoo, A., Acharya, A. N., Jena, P., Moonis, M., Biswal, J. P., Swain, S., and Tripathy, M. C. Zirconium ferrite nanoparticles as smart materials for energy and environmental applications: fractional-order supercapacitors, reservoirs of F− ions, and efficient electrocatalysts for water splitting. Nanoscale Advances, vol. 7, p. 6575-6595, 2025.
[21] Sebah, I., and Belmouden, M. Copper ferrite–graphene oxide catalyst for enhanced peroxymonosulfate activation and pollutant degradation. Nanoscale Advances, vol. 7, p. 5646, 2025.
[22] Akbar, A., Howlader, A., Islam, Q. A., Chatterjee, T., and Ghosh, M. Magnetically recoverable biogenic CuFe2O4 nanoparticles for sustainable catalytic degradation of organic dyes. Journal of Water Process Engineering, vol. 79, p. 108871, 2025.
[23] Synthiya, J. J., Arumugapriya, K., Jenila, R. M., and Shakina, J. Structural, optical, and electrochemical investigation on cobalt ferrite nanoparticles synthesized using Punica granatum peel extract. Next Materials, vol. 8, p. 100921, 2025.
[24] Suzuki, S., Takeoka, Y., Rikukawa, M., and Yoshizawa-Fujita, M. Brønsted acidic ionic liquids for cellulose hydrolysis in an aqueous medium: structural effects on acidity and glucose yield. RSC advances, vol. 8, n. 26, p. 14623-14632, 2018.
[25] Maiti, S., Sinha, S. S., Suchowski, H., and Singh, M. Process parameter optimization for the detoxification of emerging environmental pollutant, PPD. Journal of Hazardous Materials Advances, vol. 10, p. 100290, 2023.
[26] Du, M., Liu, Q., Huang, C., and Qiu, X. One-step synthesis of magnetically recyclable Co@ BN core–shell nanocatalysts for catalytic reduction of nitroarenes. RSC advances, vol. 7, n.56, p. 35451-35459, 2017.
[27] Ngo, D. T., Tran, T. T. T., Nguyen, T. L., Hoang, C. N., Tran‐Thuy, T. M., Luu, T. X.T., and Le, T. K. Microwave-assisted synthesis of magnetic CuFe2O4 nanocatalysts for rapid room-temperature reduction of 4-nitroaniline. Journal of Chemical Technology and Biotechnology, vol. 100, n. 10, p. 2163-2175, 2025.
[28] Jayachandrabal, B., Tikker, P., and Preis, S. Oxidation of aqueous p-Nitroaniline by pulsed corona discharge. Separation and Purification Technology, vol. 297,p. 121473, 2022.
[29] Jeon, K. W., Park, J. W., Lee, R. R., Gong, J. H., Jang, W. J., Shim, J. O. and Ju, Y.
W. Facile synthesis of CuFe2O4 catalyst by the electrospinning method to produce hydrogen via the water gas shift of waste-derived syngas. Journal of Environmental Chemical Engineering, vol. 11, n. 3, p. 110105, 2023.
[30] Zarei, M., Mohammadzadeh, I., Saidi, K. and Sheibani, H. Fabrication of biochar@ Cu-Ni nanocatalyst for reduction of aryl aldehyde and nitroarene compounds. Biomass Conversion and Biorefinery, vol. 14, n. 2, p. 2761-2776, 2024.
[31] Ansari, A., Badhe, R. A. and Garje, S. S. Preparation of CdS–TiO2-based palladium heterogeneous nanocatalyst by solvothermal route and its catalytic activity for reduction of nitroaromatic compounds. ACS omega, vol. 4, n. 12, p. 14937-14946, 2019.
[32] Maleki, M. H., Shirani, M. A. and Dinari, M. Facile synthesis of green and efficient copper-based magnetically recoverable nanocatalyst for the reduction of nitrophenol derivatives. Journal of Molecular Liquids, vol. 365, p. 120189, 2022. [33] Kumbhar, G. S., Patil, S. V., Sarvalkar, P. D., Vadanagekar, A. S., Karvekar, O. S., Patil, S. S., Rane, M. R., Kurhe, D. N. and Prasad, N. R. Synthesis of a Ag/rGO nanocomposite using Bos taurus indicus urine for nitroarene reduction and biological activity. RSC advances, vol. 12, n. 55, p. 35598-35612, 2022.
[34] Yulizar, Y., Apriandanu, D. O. B. and Zahra, Z. A. SiO2/NiFe2O4 nanocomposites: Synthesis, characterization and their catalytic activity for 4-nitroaniline reduction. Materials Chemistry and Physics, vol. 261, p. 124243, 2021.
[35] Naghash‐Hamed, S., Arsalani, N. and Mousavi, S. B. The catalytic reduction of nitroanilines using synthesized CuFe2O4 nanoparticles in an aqueous medium. ChemistryOpen, vol. 11, n. 11, p. e202200156, 2022.